1-(2-Aminoethyl)-3-phenylthiourea
نویسندگان
چکیده
In the crystal structure of the title compound, C(9)H(13)N(3)S, mol-ecules are linked through N-H⋯S and N-H⋯N hydrogen bonds, forming hydrogen-bonded tapes along the b axis. The dihedral angle between the phenyl ring and the thiourea group is 44.9 (2)°.
منابع مشابه
[μ-N,N′-Bis(2-aminoethyl)ethane-1,2-diamine-κ4 N 1,N 1′:N 2,N 2′]bis{[N,N′-bis(2-aminoethyl)ethane-1,2-diamine-κ4 N,N′,N′′,N′′′]cadmium} tetrakis(perchlorate)
The centrosymmetric dinuclear cadmium title complex, [Cd(2)(C(6)H(18)N(4))(3)](ClO(4))(4), was obtained by the reaction of N,N'-bis-(2-amino-eth-yl)ethane-1,2-diamine (trien) with Cd(NO(3))(2)·4H(2)O and sodium perchlorate in methanol. The Cd(II) cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octa-hedral...
متن کامل1-{2-[(Anthracen-10-yl)methyleneamino]phenyl}-3-phenylthiourea
The title compound, C(28)H(21)N(3)S, crystallizes with two mol-ecules in the asymmetric unit. There are only very slight differences in the torsion angles between the two molecules. The two mol-ecules are stabilized by intra-molecular N-H⋯N inter-actions and the crystal packing is stabilized by inter-molecular N-H⋯S inter-actions.
متن کامل1-Benzoyl-3-ethyl-3-phenylthiourea
In the title compound, C(16)H(16)N(2)OS, the conformation at the two partially double C-N bonds of the thio-urea unit is E. The amide group is twisted relative to the thio-urea fragment, forming a dihedral angle of 62.44 (16)°, and the two phenyl rings form a dihedral angle 75.93 (18)°. In the crystal, mol-ecules are linked by N-H⋯S hydrogen bonds, forming centrosymmetric dimers.
متن کامل1-Furoyl-3-methyl-3-phenylthiourea
The title compound, C(13)H(12)N(2)O(2)S, crystallizes with two independent mol-ecules in the asymmetric unit. The two mol-ecules differ in the conformation of the thio-carbonyl and carbonyl groups, and show the typical geometric parameters of substituted thio-urea derivatives. The crystal structure is mainly stabilized by inter-molecular N-H⋯O hydrogen bonding.
متن کامل[rac-2-(1-Aminoethyl)phenyl-κ2 C 1,N](ethylendiamine-κ2 N,N′)palladium(II) 3-methylbenzoate monohydrate
In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl-enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, the 3-methyl-benzoate anion and the hydrate water mol-ecule are inter-connected by N-H⋯O and O-H⋯O ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011